Reactivity in Molecular Crystals

大橋裕二・編
シリーズ:
英文書シリーズ

Reactivity in Molecular Crystals

発行
1993
サイズ
B5変型
ページ数
360
ISBN
978-4-06-206228-2
本体
14,563円(税別)
在庫
在庫無し

内容紹介

<英文書>
分子性結晶の反応に関する最新の専門書。結晶構造予測の理論、X線構造解析をはじめとする種々の分析装置、結晶相反応、固相有機反応、立体選択的光化学反応、反応経路や分子集合体の反応を20名余で解説。海外提携先:VCH

目次

1. THEORETICAL APPROACH

1.1 Potential Energy Calculations of Crystals
1.2 A Novel Molecular-Dynamics Method to Predict Molecular Crystal Structures

2. PHYSICO-CHEMICAL APPROACH

2.1 Development of a New X-ray Diffractometer (IPD-WAS) for Rapid Measurement
2.2 Reaction Process in Solid State Studied by High Resolution Electron Spectromicroscopy
2.3 Analysis of Charge Transfer Complex Formation in the Solid State by Penning Ionization Electron Spectroscopy
2.4 Analysis of Reactive Species by Time Resolved Infrared Reflection Absorption Spectroscopy
2.5 Molecular Motion in Clathrate Crystals Analyzed by Solid-state NMR Method
2.6 Asymmetric Structure Analysis for Reaction Centers of a Molecular Crystal and on a Crystal Surface by EXAFS Spectroscopy
2.7 Excitation Energy Transfer Between Metal Complexes in Solids

3. CRYSTALLINE-STATE REACTION

3.1 Dynamic Structure Analysis of Crystalline-state Reaction
3.2 Reversible Intercalation of Guest Molecules in Crystals of Cholic Acid
3.3 How can Crystalline Environment Provide Outstanding Chemistry for Diarylcarbenes or Arylnitrenes

4. SOLID-TO-SOLID ORGANIC REACTIONS

4.1 Introduction
4.2 Pinacol and Benzylic Acid Rearrangement
4.3 Baeyer-Villiger Oxidation
4.4 Reduction with NaBH4
4.5 Grignard, Reformatsky and Luche Reactions
4.6 Coupling Reactions
4.7 Witting-Horner Reaction
4.8 Aldol Condensation
4.9 Dehydration, Rearrangement, Chlorination and Etherification of Secondary Alcohols
4.10 Host-Guest Inclusion Complexation in the Solid State

5. STEREOSELECTIVE SOLID-STATE PHOTOREACTlON

5.1 Determining Factors of Molecular Arrangement and Reaction Course in the Crystalline-state Photoreaction of Unsymmetrically Substituted Diolefins
5.2 Stereoselectivity in Reactions of Clathrate Crystals
5.3 Solid-state Photochromism of Tetraphenyldihydro-1,3,5-triazine and Related Heterocycles
5.4 Solid-state Photoracemization and Photoisomerization of Alkyl Cobalt Complexes

6. REACTIVITY AND CRYSTAL STRUCTURE

6.1 Packing Effect in Solid-State Polymerization of Diethynylbenzene Derivatives by Radiation
6.2 High Selective Reaction Deduced by Tunneling Effect in the Crystalline Environment
6.3 Formation of Bimolecular Films and Crystal Structure
6.4 Reactivity and Reaction Pathway of the Sulfur Compounds
6.5 Stereoselectivily and Molecular Recognition in Double Macrocyclic Inclusion Crystals