Catalytic Science and Technology, Vol. 1


Catalytic Science and Technology, Vol. 1



サブタイトル: Proceedings of the First Tokyo Conference on Advanced Catalytic Science and Technology, Tokyo, July 1--5, 1990



I. Plenary Lectures

1. Industrial Catalysts : Poised for a New Generation of Major Innovations
2. Adsorbate Induced Restructuring of Surfaces During Catalytic Reactions. The Dynamic Surface Structure Model of Reactivity
3. Zeolitic Catalysis as Useful Tools for the Formation and the Cleavage of C-O Bonds in Fine Chemicals
4. Strategic Development of Catalytic Process : Development and Commercialization of Hydroformylation Technology
5. C-1 Chemistry : a Critical Review

II. Oral Presentations

6. A Study on the Reaction Mechanism of Methanol Conversion to Hydrocarbons by Solid State NMR and GAS Chromatography on a SAPO-34 Catalyst
7. Highly Selective Synthesis of Light Olefins from Methanol on the Novel Metal-Containing Silicoaluminophosphate
8. Molecular Shape Selectivity in Molecular Sieve Zeolites
9. Toluene Alkylation over Pre-Coke ZSM-5 Zeolite
10. Preparation of Sulfate Promoted Zirconium Pillared Montmorillonite : An Attempt to Explain the Super-Acidity
11. Molecular Approaches in Heterogeneous Catalysis Ship-in-bottle Synthesis of Zeolite-Entrapped Metal/Alloy Clusters
12. Generation of Molecular Hydrogen Origin Acid Sites on Zirconium Oxide Modified by Platinum and Sulfate Ion
13. Selective Hydrogenation of Methylacetylene
14. Hydrogenation of Alkenes on Supported PdAu Clusters
15. Hydrogenation of Carbon Monoxide on Pt/L-Zeolite Catalysts
16. Cobalt-Manganese Bimetallic Catalysts Prepared from Solvated Metal Atoms:Layered Structures Examined by X-ray Photoelectron Spectroscopy
17. Effect of TiO2-Modified Al2O3 on Dispersion and Chemical Behaviour of Supported MoO3 Catalyst
18. Surface Design of Supported Molybdenum Catalysts:Physico-Chemical Properties of Oxidized, Reduced, and Sulfided MoO3/TiO2
19. Stable Carbene Complexes on the Surface of Photoreduced Silica-Molybdena Catalysts for Olefin Metathesis
20. Activity and Durability of Natural Zeolite Containing Cupric Ions for NO Reduction by NH3
21. Decomposition of N2O and Formation of a Specific State of Surface Oxygen over Fe ZSM-5 Zeolite
22. Automotive Exhaust Catalysts Based on Cu : a Surface Science Study
23. Desox Process : Sox Emission Control from Fluid Catalytic Cracking (FCC) Regenerator
24. An FT-IR Study of the Reaction of NO with Adsorbed Ammonia on the Surface of Vanadia-Titania De-NOxing Catalysts
25. Heat Resistance of Hexaaluminate Catalyst for High-Temperature Catalytic Combustion
26. Control of Pd Dispersion in SnO2-Based Sensors
27. The Role of Antimony Oxide in Selective Oxidation Multicomponent Catalysts
28. Shape Selectivity in Epoxidation of Alkenes over Titanosilicate and Supported Titanium Catalysts
29. The Effect of Vanadium Oxide Surface Structure in the Selective Oxidation of Ethanol and Ethane
30. Selective Oxidation of Light Alkanes : Comparison between Vanadyl Pyrophosphate and V-Molybdophosphoric Acid
31. The Partial Oxidation of Cyclohexane by Activated Oxygen during the Fuel Cell Reactions of O2 and H2
32. Formation and Further Reactions of Alcohols over Platinum Supported on Niobia-Modified Alumina
33. Oxidative Coupling of Methane over Ternary and Quaternary Catalysts Derived from Li/MgO
34. Hydrogenation of Carbon Monoxide over Co-Ir-Sr/SiO2 Catalysts
35. A Mechanistic Kinetic Model for the Distribution of C-2 Oxygenate Products in the Higher Alcohol Synthesis
36. Novel Niobate Photocatalysts with Ion-Exchangeable Layered Structure
37. Structures and Catalysis of Plane [PtMo6O24] Polyanion Supported on Al2O3 and SiO2
38. Heteropoly Anion-Modified Palladium Catalyst for Reductive Carbonylation of Nitrobenzene
39. Catalytic Properties of Lanthanide (Eu and Yb)-Containing Bimetallic Catalysts
40. An Expert System for the Design of Multi-Functional Catalysts
41. The Nature of Metal Oxide Supported on gamma-Al2O3 : An Incorporation Model
42. Multifunctional Catalysis Based on Vectorial Electron and Ion Transfer

III. Poster Presentations――Industrial

43. High Platinum Loading Carbon-Supported Pt-Fe-Co Alloy Electrocatalyst for Advanced Phosphoric Acid Fuel Cell
44. Performance of a Steam Methane Reforming Catalyst (Ni) with High Activity in a 220kW Air-Cooled Phosphoric Acid Fuel Cell Demonstration Plant
45. The Design of Catalysts and Catalytic Processes for the Steam Reforming of Hydrocarbon Feedstocks
46. A New Sulfur Resistant Catalyst for CO Methanation
47. Development of C448, a High-activity Desulfurization Catalyst : from Basic Studies to Commercial Experience
48. Bead- and Honeycomb-Type Supported Gold Catalysts for the Removal of Carbon Monoxide from Air at Room Temperature
49. The Effect of Complex Oxides in Ce-La and Ce-Zr Systems on Thermal Resistant Automotive Three-Way Catalyst
50. Thermal Resistant gamma-Alumina Catalyst Support Modified with Rare Earths
51. Recovery of Chlorine from Hydrogen Chloride : MT-Chlor Process Development
52. New Guard Catalyst for De-Scaling and De-Iron
53. Development of Resid Hydrocracking Catalyst Containing Fe Supported Zeolite
54. Liquification of Plastics
55. New Vapor Phase Process for Ethylenimine Production by Catalytic Intramolecular Dehydration of Monoethanolamine
56. Alkylation Reactions over Large Pore Zeolites
57. Diol Synthesis by Noble Metal Catalyst
58. Hydroformylation of Propylene in Aqueous Phase Catalyzed over Rhodium Complexes Immobilized on PS/DVB Containing DPPDS
59. Hydrogenation of Maleic Anhydride to gamma-Butyrolactone
60. The Highly Active Ziegler-Natta Catalyst System : Catalyst Performance and Physicochemical Characterization
61. C4 Separation Process via MTBE Based on Highly Selective Catalyses
62. New Route to Liquid Crystal Monomers : Shape Selective Alkylation of Polynuclear Aromatics with Olefins
63. Studies on Rejuvenation of Spent Catalysts : a Comparative Study of the Efficiency of Three Different Organic Acids for Selective Leaching of Metal Foulants from Spent Residue Hydroprocessing Catalysts
64. Activities in the First Decade of the Committee on Reference Catalyst, The Catalysis Society of Japan
65. The UOP-BP Cyclar Process

IV . Poster Presentations――General

66. New Xenon Adsorption Method for Precise Determination of the Average Size of Metal Clusters Supported on Y Zeolite
67. Characterization of Zeolite-Supported Bimetallic Catalyst by Xenon-129 NMR
68. Molecular Dynamics Simulation of Hydrocarbons in Zeolites
69. Promoting Effect of Hydrogen Sulfide for Hydrocarbon Conversions over Alkali Metal Zeolites
70. The Selective Aromatization of Propane over HZSM-5 and Modified HZSM-5 Zeolites
71. Catalytic Hydration of Lower Olefins over Proton-Exchanged Zeolite
72. Catalytic Properties of ZSM-5 Self-Bonded Pellets
73. Catalytic Performances of Metallosilicates Prepared by Atom-Planting Method
74. Catalytic Property of Alumina-Pillared Montmorillonite Having Various Lateral Distances : Shape Selectivity in m-Xylene Conversion
75. Dehydrogenation of Methanol over Cu-Exchanged Clay Catalysts
76. Anthraquinone Synthesis from Benzene and Phthalic Anhydride over Solid Acid Catalysts
77. Selective Preparation of Primary and Secondary Amines on Skeletal Nickel and Alumina Supported Platinum and Copper Catalysts
78. Ruthenium Promoted Nickel-Molybdate Catalysts for Advanced Hydrotreating
79. The Effect of Hydrogen Sulfide on Acridine Hydrodenitrogenation on a Sulfided NiMo/Al2O3 Catalyst
80. Oxidative Coupling of Methane over Alumina Supported Lead Oxide Catalysts and Additive Effect
81. Methane Oxidative Coupling over Lead Oxide Supported Catalysts
82. Partial Oxidation of CH4, C2H6 and C2H4 by O2 over Magnesium Oxide at Room Temperature
83. Catalytic Oxidation and Ammoxidation of Propane to Produce Acrolein and Acrylonitrile
84. Layered Metal Oxyhalides : an Advanced Material for Catalytic Alkane Oxidation
85. Effect of Morphology of (VO)2P2O7 Crystallites on Catalytic Performance for Selective Oxidation of n-Butane to Maleic Anhydride
86. Liquid Phase Oxidation of Benzene to Phenol over Supported Metal Salts
87. Multicomponent Molybdenum Oxides as Selective Catalyst for Oxidation of Isobutylene to Methacrolein
88. The Role of Chlorine Adsorption on Silver Catalysts
89. The Activation of Oxygen Molecules on Sn-Modified Rh/SiO2 Catalysts
90. The Effect of Pt Catalyst and La-Dopant on the O2 Sensitivity of SrSnO3 Support
91. Nickel Catalysts for Internal Reforming in Fuel Cells
92. The Synthesis of 2-Methylpropanol from CO and H2 over CeO2 Catalysts
93. Formation of CO Hydrogenation Active Sites in the Thermal Decomposition of ZrO2-Supported Rh and Mo Carbonyl Complexes
94. The Effect of Promoters to a Cu/ZnO/Al2O3 Based Catalyst in Methanol and Higher Alcohols Synthesis from CO+H2
95. Mechanism of Methanol Synthesis from CO2 and H2 over Cu/ZnO at Atmospheric Pressure
96. Influence of Pr Ions on the Properties of Pd Supported on Graphite and Diamond via Organometallic Precursors
97. Active Promotion Effects of La2O3 Addition to Cu-SiO2 Catalyst Prepared by Alkoxide Method on Steam Reforming of Methanol
98. Role of Added Alkali Metal Cations in the Hydroformylation of Propene over Silica-Supported Group VIII Metal Catalysts
99. Vapor Phase Hydroformylation over Rhodium Complex Supported on Silicagel : Dynamic in situ FT-IR Study of Surface Species
100. Carrier Effects and its Clarification of Ni Supported on Active Carbon for Carbonylation Reaction
101. Possibility of Ruthenium as a Second Generation Ammonia Catalyst : Design of the Active and Stable Ruthenium Catalyst
102. Catalytic Dehydrogenation of Cyclohexanol with Suspended Nickel Fine Particles as a New Reaction-Separation Combined Process
103. Preparation and Hydrogenation Activity of Supported Molybdenum Carbide Catalysts
104. Synthesis of Divinylbenzene by the Dehydrogenation of Diethylbenzene over Iron Based Mixed Oxide Catalysts
105. Dinuclear mu-Aminothiolato Rhodium Complexes Supported on Silica as Catalyst Precursors for Unsaturated Hydrocarbon Hydrogenation
106. New Method for the Synthesis of alpha,beta-Unsaturated Ketones over Palladium Supported on Silica with Oxygen
107. Preparation of Fine Pd Particles and Their Catalysis for Carbon-Carbon Bond Formations via Ph-Pd Species
108. Catalytic Conversion of Chlorofluorocarbons: a Synthetic Utilization of CFC-113 by Catalytic Hydrodechlorination
109. Effect of Iodine on the Platinum-Catalyzed Combustion of Residual Hydrogen in Nuclear Power Plants
110. CO Oxidation and 16O2-18O2 Equilibration Reaction at Low Temperature on Supported Gold Catalysts
111. Decomposition of NO and Combustion of CO on Ultra-fine Particles of Au Supported on Co3O4 or Al2O3
112. Metal-Support Interaction in Supported Gold Catalysts as Visualized by Computer Graphics
113. Nitric Oxide Chemisorption and Temperature Programmed Desorption Study of Bimetallic CoMo Catalysts Supported on Activated Carbon and Alumina
114. Simultaneous Catalytic Combustion and Decomposition of Methanol in a Fluidized Bed for Producing Protective Gas
115. Diversified Investigations of Crystallization of Ferrisilicate
116. Active-Site Formation in Copper-Catalyzed Synthesis of Trimethoxysilane from Silicon and Methanol
117. Monolayer V2O5/TiO2 Catalysts Prepared by HCl-Gas-Etching Method
118. Preparation and Characterization of Silica-Supported Tantalum Oxide Thin Film
119. Enhancement of Catalytic Activity of Pd and Cu Thin Film by Surface Acoustic Wave Propagated on a Ferroelectric LiNbO3 Support
120. Structure and Catalytic Properties of CrOx/ZrO2
121. Preparation of Highly Dispersed V2O5/SiO2 by CVD and Impregnation and Their Application to Photooxidation of Propylene
122. Photosynthesis of Active Species for Catalytic Metathesis and Isomerization of Butenes from Mo(CO)6 Adsorbed on Porous Vycor Glass
123. Preparation, Characterization, and Catalytic Properties of Rhodium Double Oxides Supported on Sillica
124. Characterization of Alumina Prepared by Sol-Gel Method
125. Catalytic Properties of Zirconia-Supported Fine Nickel Particles Prepared by Spray Reaction Method
126. Platinum-Tin Bimetallic Catalysts Prepared from Solvated Metal Atoms
127. Influence of Nature of the Support on the Catalytic Behavior of Supported Nickel Sulphate for Propylene Oligomerization